Aggregates of rod-coil diblock copolymers adsorbed at a surface

The behaviour of rod-coil diblock copolymers close to a surface is discussed by using extended scaling methods. The copolymers are immersed in selective solvent such that the rods are likely to aggregate to gain energy. The rods are assumed to align only parallel to each other, such that they gain a maximum energy by forming liquid crystalline structures. If an aggregate of these copolymers adsorbs with the rods parallel to the surface the rods shift with respect to each other to allow for the chains to gain entropy. It is shown that this shift decays with increasing distance from the surface. The profile of this decay away from the surface is calculated by minimisation of the total free energy of the system. The stability of such an adsorbed aggregate and other possible configurations are discussed as well.Comment: 10 pages, 11 figure

Entropy-induced Microphase Separation in Hard Diblock Copolymers

Whereas entropy can induce phase behavior that is as rich as seen in energetic systems, microphase separation remains a very rare phenomenon in entropic systems. In this paper, we present a density functional approach to study the possibility of entropy-driven microphase separation in diblock copolymers. Our model system consists of copolymers composed of freely-jointed slender hard rods. The two types of monomeric segments have comparable lengths, but a significantly different diameter, the latter difference providing the driving force for the phase separation. At the same time these systems can also exhibit liquid crystalline phases. We treat this system in the appropriate generalization of the Onsager approximation to chain-like particles. Using a linear stability (bifurcation) analysis, we analytically determine the onset of the microseparated and the nematic phases for long chains. We find that for very long chains the microseparated phase always preempts the nematic. In the limit of infinitely long chains, the correlations within the chain become Gaussian and the approach becomes exact. This allows us to define a Gaussian limit in which the theory strongly simplifies and the competition between microphase separation and liquid crystal formation can be studied essentially analytically. Our main results are phase diagrams as a function of the effective diameter difference, the segment composition and the length ratio of the segments. We also determine the amplitude of the positional order as a function of position along the chain at the onset of the microphase separation instability. Finally, we give suggestions as to how this type of entropy-induced microphase separation could be observed experimentally.Comment: 16 pages, 7 figure

Triple and quartic interactions of Higgs bosons in the two-Higgs-doublet model with CP violation

We consider the two-Higgs-doublet model with explicit CP-violation, where the effective Higgs potential is not CP-invariant at the tree-level. Three neutral Higgs bosons of the model are the mixtures of CP-even and CP-odd bosons which exist in the CP-conserving limit of the theory. The mass spectrum and tree-level couplings of the neutral Higgs bosons to gauge bosons and fermions are significantly dependent on the parameters of the Higgs boson mixing matrix. We calculate the Higgs-gauge boson, Higgs-fermion, triple and quartic Higgs self-interactions in the MSSM with explicit CP-violation in the Higgs sector and CP-violating Yukawa interactions of the third generation scalar quarks. In some regions of the MSSM parameter space substantial changes of the self-interaction vertices take place, leading to significant suppression or enhancement of the multiple Higgs boson production cross sections.Comment: 29 pages, 4 figures. Minor changes in section 3, misprints in (47) corrected. Version accepted by EPJ

Automatised full one-loop renormalisation of the MSSM I: The Higgs sector, the issue of tan(beta) and gauge invariance

We give an extensive description of the renormalisation of the Higgs sector of the minimal supersymmetric model in SloopS. SloopS is an automatised code for the computation of one-loop processes in the MSSM. In this paper, the first in a series, we study in detail the non gauge invariance of some definitions of tan(beta). We rely on a general non-linear gauge fixing constraint to make the gauge parameter dependence of different schemes for tan(beta) at one-loop explicit. In so doing, we update, within these general gauges, an important Ward-Slavnov-Taylor identity on the mixing between the pseudo-scalar Higgs, A^0, and the Z^0. We then compare the tan(beta) scheme dependence of a few observables. We find that the best tan(beta) scheme is the one based on the decay A^0 -> tau^+ tau^- because of its gauge invariance, being unambiguously defined from a physical observable, and because it is numerically stable. The oft used DRbar scheme performs almost as well on the last count, but is usually defined from non-gauge invariant quantities in the Higgs sector. The use of the heavier scalar Higgs mass in lieu of tan(beta) though related to a physical parameter induces too large radiative corrections in many instances and is therefore not recommended.Comment: 34 pages, 1 figure, typos corrected, accepted for publication in Phys. Rev.

Preservation of equilibrium in orthograde and inverted body positions

The mechanism for regulation of the vertical pose with retention of equilibrium in the inverted body position was investigated

Mixed Quantum/Classical Approach for Description of Molecular Collisions in Astrophysical Environments

An efficient and accurate mixed quantum/classical theory approach for computational treatment of inelastic scattering is extended to describe collision of an atom with a general asymmetric-top rotor polyatomic molecule. Quantum mechanics, employed to describe transitions between the internal states of the molecule, and classical mechanics, employed for description of scattering of the atom, are used in a self-consistent manner. Such calculations for rotational excitation of HCOOCH3 in collisions with He produce accurate results at scattering energies above 15 cm–1, although resonances near threshold, below 5 cm–1, cannot be reproduced. Importantly, the method remains computationally affordable at high scattering energies (here up to 1000 cm–1), which enables calculations for larger molecules and at higher collision energies than was possible previously with the standard full-quantum approach. Theoretical prediction of inelastic cross sections for a number of complex organic molecules observed in space becomes feasible using this new computational tool